The Indigo League episodes were released by Viz Video, in association with Pioneer.  Except for one disc (Volume Seventeen, "Picture Perfect") every disc has three episodes on it.

The episode "Beauty and the Beach" is currently not available on DVD, most likely because it's an "extra" episode that's not officially a part of any season.

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Region One:  Indigo League | Adventures in the Orange Islands Johto Journeys | Johto League Champions | Master Quest Advanced | Advanced Challenge | Advanced Battle | Battle Frontier Diamond & Pearl | DP Battle Dimension | DP Galactic Battles | DP Sinnoh League Victors Black & White | BW Rival Destinies | BW Adventures in Unova (and Beyond) | The Series XY Movies & Specials | Tenth Anniversary | Elements Region Two:  TV Episodes | Movies & Pikachu Shorts | Pikachu The Movie Box TV Specials & ANA Shorts | Theme Song Collections Region Two Best Collection:  Pocket Monsters | Pocket Monsters Diamond & Pearl Pocket Monsters Best Wishes! + Pocket Monsters

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Individual Discs

Volume One I Choose You!  Pikachu! Number of Discs:  1 Released December 13th, 1998 Contains Episodes 001-003 "Pokémon I Choose You!" "Pokémon Emergency!" "Ash Catches a Pokémon" Order it now on Amazon.com

 

Volume Two The Mystery of Mt. Moon Number of Discs:  1 Released March 09th, 1999 Contains Episodes 004-006 "Challenge of the Samurai" "Showdown in Pewter City" "Clefairy and the Moon Stone" Order it now on Amazon.com

 

Volume Three The Sisters of Cerulean City Number of Discs:  1 Released March 09th, 1999 Contains Episodes 007-009 "The Water Flowers Of Cerulean City" "The Path To The Pokémon League" "The School Of Hard Knocks" Order it now on Amazon.com

 

Volume Four Poké-Friends Number of Discs:  1 Released May 18th, 1999 Contains Episodes 010-012 "Bulbasaur and the Hidden Village" "Charmander - The Stray Pokemon" "Here Comes The Squirtle Squad!" Order it now on Amazon.com

 

Volume Five Thunder Shock Number of Discs:  1 Released May 18th, 1999 Contains Episodes 013-015 "Mystery at the Lighthouse" "Electric Shock Showdown" "Battle Aboard the St. Anne" Order it now on Amazon.com

 

Volume Six Seaside Pikachu! Number of Discs:  1 Released July 20th, 1999 Contains Episodes 016-017, 019 "Pokémon Shipwreck!" "Island of the Giant Pokémon!" "Tentacool & Tentacruel" Order it now on Amazon.com

 

Volume Seven Psychic Surprise Number of Discs:  1 Released July 20th, 1999 Contains Episodes 020-022 "The Ghost of Maiden's Peak" "Bye Bye Butterfree" "Abra & the Psychic Showdown" Order it now on Amazon.com

 

Volume Eight Primeape Problems Number of Discs:  1 Released September 21st, 1999 Contains Episodes 023-025 "The Tower of Terror" "Haunter vs. Kadabra" "Primeape Goes Bananas" Order it now on Amazon.com

 

Volume Nine Fashion Victims Number of Discs:  1 Released September 21st, 1999 Contains Episodes 026-028 "Pokémon Scent-sation" "Hypno's Naptime" "Pokémon Fashion Flash" Order it now on Amazon.com

 

Volume Ten Fighting Tournament Number of Discs:  1 Released September 21st, 1999 Contains Episodes 029-031 "The Punchy Pokemon" "Sparks Fly for Magnemite" "Dig Those Diglett!" Order it now on Amazon.com

 

Volume Eleven The Great Race Number of Discs:  1 Released November 23rd, 1999 Contains Episodes 032-034 "The Ninja Poke-Showdown!" "The Flame Pokemon-athon!" "The Kangaskhan Kid" Order it now on Amazon.com

 

Volume Twelve Pikachu Party Number of Discs:  1 Released November 23rd, 1999 Contains Episodes 035-037 "The Bridge Bike Gang" "Ditto's Mysterious Mansion" "Pikachu's Goodbye" Order it now on Amazon.com

 

Volume Thirteen Wake Up Snorlax! Number of Discs:  1 Released January 18th, 2000 Contains Episodes 038-040 "The Battling Eevee Brothers" "Wake Up, Snorlax!" "Showdown in Dark City" Order it now on Amazon.com

 

Volume Fourteen Jigglypuff Pop Number of Discs:  1 Released January 18th, 2000 Contains Episodes 041-043 "The March of the Exeggutor Squad" "The Problem with Paras" "The Song of Jigglypuff" Order it now on Amazon.com

 

Volume Fifteen Charizard! Number of Discs:  1 Released February 22nd, 2000 Contains Episodes 044-046 "Attack of the Prehistoric Pokemon" "A Chansey Operation" "Holy Matrimony!" Order it now on Amazon.com

 

Volume Sixteen Totally Togepi Number of Discs:  1 Released February 22nd, 2000 Contains Episodes 047-049 "So Near, Yet So Farfetch'd" "Who Gets to Keep Togepi?" "Bulbasaur's Mysterious Garden" Order it now on Amazon.com

 

Volume Seventeen Picture Perfect Number of Discs:  1 Released May 30th, 2000 Contains Episodes 050-053 "The Case of the K-9 Caper" "Pokémon Paparazzi" "The Ultimate Test" "The Breeding Center Secret" Order it now on Amazon.com

 

Volume Eighteen Water Blast! Number of Discs:  1 Released May 30th, 2000 Contains Episodes 056-058 "Riddle Me This" "Vocanic Panic" "Beach Blank-Out Blastoise" Order it now on Amazon.com

 

Volume Nineteen Our Hero Meowth Number of Discs:  1 Released July 18th, 2000 Contains Episodes 054-55, 059 "Princess Versus Princess" "The Purr-fect Hero" "The Misty Mermaid" Order it now on Amazon.com

 

Volume Twenty The Final Badge Number of Discs:  1 Released July 18th, 2000 Contains Episodes 060-062 "Clefairy Tales" "The Battle of the Badge" "It's Mr. Mimie Time" Order it now on Amazon.com

 

Volume Twenty-One The Po-ké Corral! Number of Discs:  1 Released September 19th, 2000 Contains Episodes 063-065 "Holiday Hi-Jynx" "Snow Way Out" "Showdown at the Poke Corral" Order it now on Amazon.com

 

Volume Twenty-Two Hang Ten Pikachu Number of Discs:  1 Released September 19th, 2000 Contains Episodes 066-068 "The Evolution Solution" "The Pi-Kahuna" "Make Room for Gloom" Order it now on Amazon.com

 

Volume Twenty-Three Show Time! Number of Discs:  1 Released November 14th, 2000 Contains Episodes 069-071 "Lights, Camera, Quacktion!" "Go West, Young Meowth" "To Master the Onixpected" Order it now on Amazon.com

 

Volume Twenty-Four Into the Arena Number of Discs:  1 Released November 14th, 2000 Contains Episodes 072-074 "The Ancient Puzzle of Pokémopolis" "Bad to the Bone" "All Fired Up" Order it now on Amazon.com

 

Volume Twenty-Five Round One! Number of Discs:  1 Released January 23rd, 2001 Contains Episodes 075-077 "Round One-Begin!" "Fire and Ice" "Fourth Round Rumble" Order it now on Amazon.com

 

Volume Twenty-Six Friends and Rivals Number of Discs:  1 Released January 23rd, 2001 Contains Episodes 078-080 "A Friend in Deed" "Friend or Foe Alike" "Friends to the End" Order it now on Amazon.com

Box Sets

Volume One Pokémon Indigo League Number of Discs:  3 Released November 21st, 2006 Contains Episodes 001-017, 019-027 Disc One: "Pokémon!  I Choose You!" "Pokémon!  Emergency!" "Ash Catches a Pokémon!" "Challenge of the Samurai" "Showdown in Pewter City" "Clefairy and the Moon Stone" "The Water Flowers of Cerulean City" "The Path to the Pokémon League" "The School of Hard Knocks" Disc Two: "Bulbasaur and the Hidden Village" "Charmander - The Stray Pokémon" "Here Comes the Squirtle Squad" "Mystery at the Lighthouse" "Electric Shock Showdown" "Battle Aboard the St. Anne" "Pokémon Shipwreck!" "Island of the Giant Pokémon!" "Tentacool & Tentacruel" Disc Three: "The Ghost of Maiden's Peak" "Bye Bye Butterfree" "Abra and the Psychic Showdown" "The Tower of Terror" "Haunter vs. Kadabra" "Primeape Goes Bananas" "Pokémon Scent-sation" "Hypno's Naptime" Order it from Amazon.com

Volume Two Pokémon Indigo League Number of Discs:  3 Released November 13th, 2007 Contains Episodes 127-152 Disc One: "Pokemon Fashion Flash" "The Punchy Pokemon" "Sparks Fly for Magnemite" "Dig Those Diglett!" "The Ninja Poke-Showdown!" "The Flame Pokemon-athon!" "The Kangaskhan Kid" "The Bridge Bike Gang" "Ditto's Mysterious Mansion" Disc Two: "Pikachu's Goodbye" "The Battling Eevee Brothers" "Wake Up, Snorlax!" "Showdown in Dark City" "The March of the Exeggutor Squad" "The Problem with Paras" "The Song of Jigglypuff" "Attack of the Prehistoric Pokemon" "A Chansey Operation" Disc Three: "Holy Matrimony!" "So Near, Yet So Farfetch'd" "Who Gets to Keep Togepi?" "Bulbasaur's Mysterious Garden" "The Case of the K-9 Caper" "Pokémon Paparazzi" "The Ultimate Test" "The Breeding Center Secret" Order it from Amazon.com

Volume Three Pokémon Indigo League Number of Discs:  3 Released February 18th, 2008 Contains Episodes 201-227 Disc One: "Riddle Me This" "Vocanic Panic" "Beach Blank-Out Blastoise" "Princess Versus Princess" "The Purr-fect Hero" "The Misty Mermaid" "Clefairy Tales" "The Battle of the Badge" "It's Mr. Mimie Time" Disc Two: "Holiday Hi-Jynx" "Snow Way Out" "Showdown at the Poke Corral" "The Evolution Solution" "The Pi-Kahuna" "Make Room for Gloom" "Lights, Camera, Quacktion!" "Go West, Young Meowth" "To Master the Onixpected" Disc Three: "The Ancient Puzzle of Pokémopolis" "Bad to the Bone" "All Fired Up" "Round One-Begin!" "Fire and Ice" "Fourth Round Rumble" "A Friend in Deed" "Friend or Foe Alike" "Friends to the End" Order it from RightStuf.com